Electrode assembly comprising fiber-shaped structures

ABSTRACT

The present invention relates to an electrode assembly comprising fiber-shaped structures. The electrode assembly for a battery according to one embodiment of the present invention comprises: a first electrode including a plurality of first fiber-shaped structures extending in a first direction; a second electrode including a plurality of second fiber-shaped structures which extend in a second direction other than the first direction, and the polarities of which are different from the polarities of the first structures; and a first separator film interposed between the first structures and the second structures which intersect with each other, so as to separate the first structures and the second structures from each other.

TECHNICAL FIELD

The present invention relates to a battery technology, and moreparticularly, to an electrode assembly of a battery including fibrousstructures.

BACKGROUND ART

As a semiconductor manufacturing technology and a communicationtechnology have recently been developed, the mobile electronic deviceindustry has expanded, and demands for environmental preservation anddevelopment of alternative energy due to resource depletion haveincreased, batteries have been actively studied. Since lithium primarybatteries which are representative batteries have a higher voltage andhigher energy density than conventional aqueous batteries, the lithiumprimary batteries may be easily made compact and light. Such lithiumprimary batteries are widely used, for example, as main power supplysources for mobile electronic devices or backup power supply sources.

Secondary batteries are rechargeable batteries formed of an electrodematerial having high reversibility. The secondary batteries areclassified into cylindrical secondary batteries and polygonal secondarybatteries according to outer appearances, and classified intonickel/metal hydride (Ni-MH) secondary batteries, lithium (Li) secondarybatteries, and lithium-ion (Li-ion) secondary batteries according toanode and cathode materials. Devices to which secondary batteries areapplied have been diversified from small batteries such as mobilephones, notebooks, and mobile displays to medium and large batteries forelectric vehicles and hybrid vehicles. Accordingly, batteries arerequired to have high stability and cost effectiveness as well aslightweight design, high energy density, high charge/discharge speed,high charge/discharge efficiency, and excellent cycle characteristics.

DISCLOSURE OF THE INVENTION Technical Problem

The present invention provides an electrode assembly of a battery whichhas high energy density, high charge/discharge efficiency, and excellentcycle characteristics and whose shape and capacity may be easilyadjusted.

Technical Solution

According to an aspect of the present invention, there is provided anelectrode assembly including: a first electrode including a plurality offirst structures that have fibrous shape and extend in a firstdirection; a second electrode including a plurality of second structuresthat have fibrous shape and polarity opposite to polarities of the firststructures, and extend in a second direction different from the firstdirection; and a first separator that is disposed between the firststructures and the second structures which cross each other, andseparates the first structures from the second structures.

The first structures may extend on a first main surface of the firstseparator to be spaced apart from one another, and the second structuresmay extend on a second main surface of the first separator which isopposite to the first main surface to be spaced apart from one another.The electrode assembly may further include: a third electrode includinga plurality of third structures that have fibrous shape and polarityopposite to the polarity of the first structures, and extend on thefirst main surface of the first separator in the first direction toalternate with the first structures; and a fourth electrode including aplurality of fourth structures that have fibrous shape and polarityopposite to the polarity of the second structures, and extend on thesecond main surface of the first separator in the second direction toalternate with the second structures, wherein the third structures andthe fourth structures which cross each other are separated from eachother by the first separator.

At least some of the first through fourth structures may be partially ortotally buried in the first or second main surface of the firstseparator. The electrode assembly may further include: at least onesecond separator that is stacked on the first separator to form amulti-layered structure; and a third electrode including a plurality ofthird structures that extend on a main surface of the second separatorwhich is opposite to an interface between the first separator and thesecond isolation, and have fibrous shape and polarity opposite topolarity of structures of the interface, wherein the third structuresand the structures on the interface cross each other.

The electrode assembly may further include: at least one secondseparator that is stacked on the first separator to form a multi-layeredstructure; a fifth electrode including a plurality of fifth structuresthat extend on a main surface of the second separator which is oppositeto an interface between the first separator and the second separator,and have fibrous shape and polarity opposite to polarity of structureson the interface, wherein the fifth structures and the structures on theinterface cross each other; and a sixth electrode including a pluralityof sixth structures that have fibrous shape and polarity opposite to thepolarity of the fifth structures, extend on the other main surface ofthe second separator to alternate with the fifth structures, wherein thesixth structures and the structures on the interface cross each other.At least some of the first through sixth structures may be partiallyburied in the first or second separator.

The first structures and the second structures may cross each other asweft threads and warp threads reciprocating through the first separator.Each of the first structures and the second structures may include acurrent collector core and an active material layer that surrounds thecurrent collector core. Only ones of the first structures and the secondstructures may selectively further include a solid electrolyte layerthat surrounds the active material layer.

A thickness of each of the first and second structures may range from400 μm to 2,000 μm, and a distance between the first and secondstructures may range from 2 μm to 400 μm. A distance between the firstand second structures may be less than a thickness of each of the firstand second structures. The first separator may include any one of amicro-porous film, a woven fabric, a nonwoven fabric, an intrinsic solidpolymer electrolyte film, a gel solid polymer electrolyte film, and acombination thereof. The electrode assembly may be used for a primarybattery or a secondary battery.

According to another aspect of the present invention, there is providedan electrode assembly including: a first electrode including a pluralityof first structures that have fibrous shape and extend in a firstdirection, and a plurality of second structures that have fibrous shapeand the same polarity as polarity of the first structures and extend ina second direction different from the first direction to cross the firststructures; a second electrode including a plurality of third structuresthat have fibrous shape and extend in a third direction, and a pluralityof fourth structures that have fibrous shape and the same polarity aspolarities of the third structures and extend in a fourth directiondifferent from the third direction to cross the third structures; and afirst separator that separates the first electrode from the secondelectrode.

The first electrode and the second electrode may be rotated or offsetsuch that the first electrode and the second electrode are notsymmetrical with each other. The first and second structures may crosseach other as weft threads and warp threads, and the third and fourthstructures may cross each other as weft threads and warp threads. Eachof the first structures and the second structures may include a currentcollector core and an active material layer that surrounds the currentcollector core. Only one of a group of the first and second structuresand a group of the third and fourth structures may selectively furtherinclude a solid electrolyte layer.

According to another aspect of the present invention, there is providedan electrode assembly including: an isolation matrix; a first electrodeincluding a plurality of first structures that have fibrous shape, andpass through the isolation matrix and extend on a first plane in theisolation matrix in a first direction to be spaced apart from oneanother; and a second electrode including a plurality of secondstructures that have fibrous shape, and pass through the isolationmatrix and extend on a second plane, which is spaced apart from thefirst plane to be parallel to the first plane, in the isolation matrixin a second direction different from the first direction to cross thefirst structures.

The electrode assembly may further include a third electrode including aplurality of third structures that have fibrous shape and polarityopposite to polarity of the first structures, and extend on the firstplane in the first direction to alternate with the first structures; anda fourth electrode including a plurality of fourth structures that havefibrous shape and polarity opposite to polarity of the secondstructures, and extend on the second plane in the second direction toalternate with the second structures. A plurality of the first planesand a plurality of the second planes may be provided to form amulti-layered structure.

Each of the first structures and the second structures may include acurrent collector core and an active material layer that surrounds thecurrent collector core. Only ones of the first structures and the secondstructures may selectively further include a solid electrolyte layerthat surrounds the active material layer.

The isolation matrix may be any one of a micro-porous film, a wovenfabric, a nonwoven fabric, an intrinsic solid polymer electrolyte film,a gel solid polymer electrolyte film, and a combination thereof. Athickness of each of the first and second structures may range from 400μm to 2,000 μm, and a distance between the first and second structuresmay range from 2 μm to 400 μm. A distance between the first and secondstructures may be less than a thickness of each of the first and secondstructures.

According to another aspect of the present invention, there is providedan electrode assembly including: an isolation matrix; a first electrodeincluding a plurality of first structures that have fibrous shape, andpass through the isolation matrix and extend on a first plane in theisolation matrix in a first direction to be spaced apart from oneanother; and a second electrode including a plurality of secondstructures that have fibrous shape, and pass through the isolationmatrix and extend on the first plane in a second direction differentfrom the first direction such that the second structures and the firststructures cross each other as weft threads and warp threads.

The electrode assembly may further include a second cathode and a secondanode respectively including a plurality of third structures and aplurality of fourth structures which have fibrous shapes and extend on asecond plane, which is spaced apart from the first plane to be parallelto the first plane, in the isolation matrix such that the third andfourth structures and the first and second structures cross each otheras weft threads and warp threads. Each of the first structures and thesecond structures may include a current collector core and an activematerial that surrounds the current collector core. Only ones of thefirst structures and the second structures may selectively furtherinclude a solid electrolyte layer that surrounds the active materiallayer.

The isolation matrix may include an intrinsic solid polymer electrolytefilm or a gel solid polymer electrolyte film. A thickness of each of thefirst and second structures may range from 400 μm to 2,000 μm, and adistance between the first and second structures may range from 2 μm to400 μm. A distance between the first and second structures may be lessthan a thickness of the first and second structures.

According to another aspect of the present invention, there is providedan electrode assembly including: a first electrode including a pluralityof first structures that have fibrous shapes and extend in a firstdirection; a second electrode that has a planar shape and a polarityopposite to polarities of the first structures; and a separator that isdisposed between the first electrode and the second electrode.

The electrode assembly may further include a third electrode including aplurality of second structures that have fibrous shape and the samepolarity as the polarity of the first structures, and extend in a seconddirection different from the first direction to cross the firststructures. The first structures and the second structures may crosseach other as weft threads and warp threads. The first and secondstructures may reciprocate through the separator.

The first structures may further extend to surround both main surfacesof the second electrode. A thickness of each of the first structures mayrange from 400 μm to 2,000 μm, and a distance between the firststructures may range from 2 μm to 400 μm. A distance between the firststructures may be less than a thickness of each of the first structures.

The present also provides a battery having the electrode assembly. Thebattery having the electrode assembly may be a primary battery or asecondary battery.

Advantageous Effects

According to the one or more embodiments of the present invention, sinceat least some electrodes include a plurality of structures havingfibrous shapes, an interfacial surface area between the electrodes maybe increased due to curved surfaces and 3D arrangements of thestructures. Accordingly, battery energy density in the same volume maybe improved, and charge/discharge speed, charge/discharge efficiency,and battery cycle characteristics may also be improved.

Also, since fibrous structures constitute electrodes, a shape of abattery may be easily changed. Since capacity may be easily adjusted bybending or stacking the battery, the battery may be easily used as asmall battery or a large or medium battery.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view illustrating an electrode assembly of abattery, according to an embodiment of the present invention;

FIG. 2 is a perspective cross-sectional view illustrating fibrousstructures, according to other embodiment of the present invention;

FIG. 3 is a perspective view illustrating an electrode assembly of abattery, according to another embodiment of the present invention;

FIG. 4 is an exploded perspective view illustrating an electrodeassembly of a battery, according to another embodiment of the presentinvention;

FIG. 5 is an exploded perspective view illustrating an electrodeassembly of a battery, according to another embodiment of the presentinvention;

FIGS. 6A through 6C are perspective views illustrating an electrodeassembly according to another embodiment of the present invention;

FIG. 7 is a perspective view illustrating an electrode assembly of abattery, according to another embodiment of the present invention;

FIG. 8 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention;

FIG. 9 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention;

FIG. 10 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention;

FIG. 11 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention;

FIG. 12 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention; and

FIG. 13 is a perspective view illustrating an electrode assemblyaccording to another embodiment of the present invention.

MODE FOR CARRYING OUT THE INVENTION

The present invention will now be described more fully with reference tothe accompanying drawings, in which exemplary embodiments of theinvention are shown.

The present invention now will be described more fully hereinafter withreference to the accompanying drawings, in which elements of theinvention are shown. The present invention may, however, be embodied inmany different forms and should not be construed as limited to theexemplary embodiments set forth herein. Rather, these embodiments areprovided so that this disclosure will be thorough and complete, and willfully convey the scope of the present invention to one of ordinary skillin the art.

Also, in the drawings, thicknesses or sizes of layers are exaggeratedfor convenience of explanation and clarity, and the same referencenumerals denote the same elements. As used herein, the term “and/or”includes any and all combinations of one or more of the associatedlisted items.

The terminology used herein is for the purpose of describing particularembodiments only and is not intended to be limiting of exemplaryembodiments of the present invention. As used herein, the singular forms“a”, “an” and “the” are intended to include the plural forms as well,unless the context clearly indicates otherwise. It will be furtherunderstood that the terms “comprises”, “comprising,”, “includes” and/or“including”, when used herein, specify the presence of stated features,integers, steps, operations, elements, and/or components, but do notpreclude the presence or addition of one or more other features,integers, steps, operations, elements, components, and/or groupsthereof.

It will be understood that, although the terms first, second, third etc.may be used herein to describe various elements, components, regions,layers, and/or sections, these elements, components, regions, layers,and/or sections should not be limited by these terms. These terms areonly used to distinguish one element, component, region, layer, orsection from another region, layer, or section. Thus, a first element,component, region, layer, or section discussed below could be termed asecond element, component, region, layer, or section without departingfrom the teachings of exemplary embodiments.

The embodiments of the present invention provide an electrode assemblyincluding an electrode including a plurality of fibrous structures whichmay increase an interfacial surface area between electrodes as comparedto a conventional two-dimensional (2D) battery structure in which aplate-type anode and a plate-type cathode face each other.

When the expression ‘different direction’ is used herein, it means thatwhen an anode including a plurality of fibrous structures and a cathodeincluding a plurality of fibrous structures are stacked or wound to forman electrode structure, the fibrous structures of any one electrodeextend in an arbitrary direction other than a direction in which thefibrous structures of the other electrode extend. That is, the pluralityof fibrous structures constituting the anode and the cathode may havestructural flexibility high enough to be arranged at various angles andin various directions.

Also, when the expression ‘cross each other’ is used herein, it meansthat when an anode including a plurality of fibrous structures and acathode including a plurality of fibrous structures are stacked or woundto form an electrode structure, the fibrous structures of the anode andthe cathode are arranged to have at least one point where they meet eachother, which is different from a conventional structure in which ananode and a cathode are stacked or arranged in the same direction.

Also, when the term ‘separator’ is used herein, the separator includes aseparator that is generally commonly used in a liquid electrolytebattery using a liquid electrolyte having affinity with the separator.Furthermore, when the separator used herein includes an intrinsic solidpolymer electrolyte and/or a gel solid polymer electrolyte which is sostrongly bound to the separator that the electrolyte and the separatorare recognized as the same. Accordingly, the meaning of the separatorhas to be defined as described herein.

FIG. 1 is a perspective view illustrating an electrode assembly 100 of abattery, according to an embodiment of the present invention. FIG. 2 isa perspective cross-sectional view illustrating first and secondstructures 111 and 121 having fibrous shapes, according to an embodimentof the present invention.

Referring to FIG. 1, the electrode assembly 100 constituting the batteryincludes a plurality of the first and second structures 111 and 121 anda separator 130. The first structures 111 may extend in parallel, andthe second structures 121 may extend in parallel. The first structures111 may extend in an x direction, and the second structures 121 mayextend in a y direction different from the x direction.

The first structures 111 and/or the second structures 121 may extend inparallel to be spaced apart from one another by a distance ‘d’ as shownin FIG. 1. Each of the first structures 111 and/or the second structures121 may have a thickness w enough to provide forming processabilitysuitable for various arrangements of the first and second structures 111and 121. For example, the thickness w of the first and second structures111 and 121 may range from 400 μm to 2,000 μm, and may be appropriatelydetermined according to a field to which the battery is applied. Thedistance d may be greater than 0 μm and less than 1,000 μm, andpreferably, from 2 μm to 400 μm. As described below, in order toincrease an interfacial surface area between electrodes, the distance dmay be greater than 0 μm and less than the thickness w of the first andsecond structures 111 and 121.

The first structures 111 extending in one direction in parallel may beelectrically connected to one another to constitute one electrode, forexample, a cathode 110. Likewise, the second structures 121 may beelectrically connected to one another to constitute another electrodehaving a different polarity, for example, an anode 120.

Although the first structures 111 and the second structures 121 extendperpendicular to each other in FIG. 1, the present embodiment is notlimited thereto. For example, the first and second structures 111 and121 having fibrous shapes may extend with an angle of about 45° or 60°therebetween.

Referring to FIG. 2, the first and second structures 111 and 121 mayinclude anode and cathode current collector cores 112 a and 112 b andanode and cathode active material layers 113 a and 113 b that surroundthe anode and cathode current collector cores 112 a and 112 b. The anodeand cathode active material layers 113 a and 113 b may be respectivelycoated on the anode and cathode current collector cores 112 a and 112 bwith slurries including a corresponding active material, a binder, and aconductive material. Each of the slurries may include the correspondingactive material in an amount of 80 to 98 wt %, the binder in an amountof 1 to 10 wt %, and the conductive material in an amount of 1 to 10 wt% based on 100 wt %.

A thickness of the anode active material layer 113 a may range from 1 μmto 300 μm, and preferably, from 30 μm to 100 μm. A thickness of thecathode active material layer 113 b may range from 3 μm to 100 μm, andpreferably, from 3 μm to 40 μm, and more preferably, from 5 μm to 20 μm.Since a thickness of the cathode active material layer 113 b isdetermined in the aforesaid range, the battery may ensure high outputand may be made very thin. When a thickness of the cathode activematerial layer 113 b is less than 3 μm, the effect of retarding internalshort-circuit may be degraded, and when the battery is a lithium-ionsecondary battery, high output may not be ensured. Also, when athickness of the cathode active material layer 113 b is greater than 100μm, the battery may not be made thin.

The anode and cathode current collector cores 112 a and 112 b may be,for example, soft metal lines. For example, the cathode currentcollector core 112 a may be formed of a metal-based material such asstainless steel, titan, aluminum, or an alloy thereof. Preferably, thecathode current collector core 112 a may be formed of aluminum or analloy thereof. The anode current collector core 112 b may be formed of ametal-based material such as copper, stainless steel, nickel, or analloy thereof. Preferably, the anode current collector core 112 b may beformed of copper or an alloy thereof.

However, the present embodiment is not limited thereto, and each of thecathode and anode current collector cores 112 a and 112 b may include amaterial whose shape may be easily changed, for example, a polymermaterial having electronic conductivity such as poly(sulfurnitrile),polypyrrole, poly(p-phenylene), poly(phenylene sulfide), polyaniline, orPoly(p-phenylenevinylene). Alternatively, each of the cathode and anodecurrent collector cores 112 a and 112 b may be formed of a fibrousmaterial obtained by mixing a conductive carbon paste, a nano metalparticle paste, or an indium tin oxide (ITO) paste with a binder.

Although the cathode and anode current collector cores 112 a and 112 bof FIG. 2 have circular cross-sectional shapes in FIG. 2, the presentembodiment is not limited thereto. For example, the cathode and anodecurrent collector cores 112 a and 112 b may have arbitrary shapes thatmay allow the cathode and anode active material layers 113 a and 113 bto be easily attached to the anode and cathode current collector cores112 a and 112 b. For example, the cathode and anode current collectorcores 112 a and 112 b may have predetermined surface roughnesses andarbitrary cross-sectional shapes, for example, square or ovalcross-sectional shapes, whose surface curvature change ranges from 60%to 140%.

The active material layer 130 may include a material layer suitable fora primary battery or a secondary battery. For example, when the batteryis a primary battery, the cathode active material layer 113 a mayinclude manganese oxide, electrolytic manganese dioxide (EMD), nickeloxide, lead oxide, lead dioxide, silver oxide, iron sulfate, orconductive polymer particles, and the anode active material layer 113 bmay include zinc, aluminum, iron, lead, or magnesium particles.

When the battery is a secondary battery, the cathode active materiallayer 113 a may include a Li compound including at least one metal ofNi, Co, Mn, Al, Cr, Fe, Mg, Sr, V, La, and Ce, and at least one nonmetalelement selected from the group consisting of O, F, S, P and acombination thereof. For example, the cathode active material layer 113a may include a compound represented by LiaAl-bBbD2, where A is selectedfrom the group consisting of Ni, Co, Mn, and a combination thereof, B isselected from the group consisting of Al, Ni, Co, Mn, Cr, Fe, Mg, Sr, V,a rare earth element, and a combination thereof, and D is selected fromthe group consisting of O, F, S, P, and a combination thereof, and0.95≦a≦1.1 and 0≦b≦0.5.

When the battery is a secondary battery, the anode active material layer113 b may include a carbon-based material such as a low-crystallizedcarbon or high-crystallized carbon-based material which can intercalateand deintercalate lithium ions. The low-crystallized carbon may be softcarbon or hard carbon. The high-crystallized carbon may be naturalgraphite or high temperature baked carbon such as Kish graphite,pyrolytic carbon, mesophase pitch-based carbon fiber, meso-carbonmicrobeads, Mesophase pitches, or petroleum or coal tar pitch-derivedcokes. The anode active material layer 113 b may include a binder, andthe binder may be a polymer material such as vinylidenefluoride-hexfluoropropylene copolymer (PVDF-co-HFP),polyvinylidenefluoride, polyacrylonitrile, or polymethylmethacrylate.Alternatively, in order to provide a high-capacity secondary battery,the cathode active material layer 113 b may include a metal-based orintermetallic compound including S, Si, or Sn.

Although the current collector cores 112 a and 112 b and the activematerial layers 113 a and 113 b are separately formed in FIG. 2, thepresent embodiment is not limited thereto: any current collector coreand a corresponding active material layer of at least one of the firststructures 111 and the second structures 121 may be formed of the samematerial.

In one example, only one of the first and second structures 111 and 121may further include a solid electrolyte layer such as an intrinsic solidpolymer electrolyte layer. The solid electrolyte layer may be formed byusing a consecutive impregnation process using the same solvent as thatused to form an active material layer disposed under the solidelectrolyte layer. The solid electrolyte layer may include, for example,a polymer matrix composed of any one of polyethylene, polypropylene,polyimide, polysulfone, polyurethane, polyvinyl chloride, polystyrene,polyethylene oxide, polypropylene oxide, polybutadiene, cellulose,carboxymethyl cellulose, nylon, polyacrylonitrile, polyvinylidenefluoride, polytetrafluoroethylene, a copolymer of vinylidene fluorideand hexafluoropropylene, a copolymer of vinylidene fluoride andtrifluoroethylene, a copolymer of vinylidene fluoride andtetrafluoroethylene, polymethylacrylate, polyethylacrylate,polymethylmethacrylate, polyethylmethacrylate, polybutylacrylate,polybutylmethacrylate, polyvinyl acetate, polyvinyl alcohol, and acombination thereof, an additive, and an electrolytic solution. Theadditive may be silica, talc, alumina (Al2O3), TiO2, clay, zeolite, or acombination thereof. The electrolytic solution may be an aqueouselectrolytic solution including salt such as potassium hydroxide (KOH),potassium bromide (KBr), potassium chloride (KCL), zinc chloride(ZnCl2), or sulfuric acid (H2SO4).

In FIG. 2, only the second structures 121 further each include a solidelectrolyte layer 114 such as an intrinsic solid polymer electrolyte. Assuch, since the solid electrolyte layer 114 is formed on structures ofany of the cathode 110 and the anode 120, a volume may be reduced whencompared to a case where the solid electrolyte layer 114 is formed onstructures of both the cathode 110 and the anode 120, thereby furtherimproving energy density. Also, assuming that the first structures 111of the cathode 110 and the second structures 121 of the anode 120 crosseach other, if the solid electrolyte layer 114 is formed on both thecathode 110 and the anode 120, cracks may occur in the solid electrolytelayer 114 due to a change in a volume of the electrode assembly 100while a secondary battery is charged or discharged, thereby reducing thelifetime of the electrode assembly 100. Accordingly, preferably, thesolid electrolyte layer 114 may be selectively formed only on thestructures of one electrode whose volume change is smaller during itscharging/discharging than other electrode. For example, when the batteryis a secondary battery, the solid electrolyte layer 114 may beselectively formed only on the second structures 121 of the anode 120whose volume change is relatively small during charging/discharging asshown in FIG. 2.

Referring back to FIG. 1, the separator 130 may have a layered shape,and is disposed between the first structures 111 constituting thecathode 110 and the second structures 121 constituting the anode 120.The separator 130 may be, for example, a micro-porous film, a wovenfabric, a nonwoven fabric, an intrinsic solid polymer electrolyte film,or a gel solid polymer electrolyte film. The intrinsic solid polymerelectrolyte film may include a straight chain polymer material or across-linked polymer material. The gel polymer electrolyte film may beany one of a plasticizer-containing polymer including salt, afiller-containing polymer, and a pure polymer, or a combination thereof.

The above-listed materials for the separator 130 are exemplary, and anyappropriate electronic insulating material whose shape may be easilychanged and have appropriate ionic conductivity, and which has highmechanical strength and may not be broken or cracked even when theelectrode assembly 100 is deformed may be used for the separator 130.The separator 130 may be a single-layered film or a multi-layered film.The multi-layered film may be a stack of single-layered films formed ofthe same material or a stack of films formed of different materials. Athickness of the separator 130 may range from 10 μm to 300 μm,preferably, from 10 μm to 40 μm, and more preferably, from 10 μm to 25μm in consideration of durability, shut-down function, and batterystability.

As described above, the first structures 111 constituting the cathode110 and the second structures 121 constituting the anode 120 extend indifferent directions, and cross each other in different directions withthe separator 130 therebetween. Since the first and second structures111 and 121 of the cathode 110 and the anode 120 have curved surfacesand are arranged in a three-dimensional (3D) manner and cross each otherwith the separator 130 therebetween, an interfacial surface area betweenthe cathode 110 and the anode 120 may be increased. As a result, energydensity in the same volume may be improved, and charge/discharge speed,charge/discharge efficiency, and battery cycle characteristics may alsobe improved.

FIG. 3 is a perspective view illustrating an electrode assembly 200 of abattery, according to another embodiment of the present invention.

Referring to FIG. 3, the electrode assembly 200 includes a plurality offirst through fourth structures 111 a, 121 a, 121 b, and 111 b havingfibrous shapes, and the separator 130. The first structures 111 a andthe second structures 121 a which extend in parallel in one directioncorrespond to the first and second structures 111 and 121 of theelectrode assembly 100 illustrated in FIG. 1. The first and secondstructures 111 a and 121 a are coupled to each other and mayrespectively constitute a first cathode 110 a and a first anode 120 a ofthe battery.

The electrode assembly 200 of FIG. 3 further includes the thirdstructures 121 b that have fibrous shapes and extend on a first mainsurface 130 a of the separator 130 in the same direction as the firststructures 111 a to alternate with the first structures 111 a. Likewise,the electrode assembly 200 may further include the fourth structures 111b that have fibrous shapes and extend on a second main surface 130 b ofthe separator 130 in the same direction as the second structures 121 aof the anode 120 a to alternate with the second structures 121 a.

The third structures 121 b and the fourth structures 111 b may haverespectively polarity opposite to that of the first structures 111 a andthe second structures 121 a which are respectively adjacent to the thirdstructures 121 b and the fourth structures 111 b. For example, the thirdstructures 121 b may constitute a second anode 120 b and the fourthstructures 111 b may constitute a second cathode 110 b.

The first cathode 110 a and the second cathode 110 b may be coupled toeach other with leads to constitute one single common cathode. Likewise,the first anode 120 a and the second anode 120 b may be electricallycoupled to each other to constitute one single common anode. However, itis exemplary and the present embodiment is not limited thereto. Forexample, any one of the first cathode 110 a and the second cathode 110 band any one of the first anode 120 a and the second anode 120 b may becoupled to each other, and the remaining cathode and anode may beprovided as external electrodes to provide a bipolar battery. Also, itwould be understood by one of ordinary skill in the art that any ofvarious bipolar batteries for increasing an operating voltage may beprovided by appropriately selecting the number and arrangement ofstructures having opposite polarities, coupling the structures in seriesin the battery, and providing remaining structures as a cathode and ananode.

In order to ensure stable insulation between adjacent structures havingopposite polarities, some of the first through fourth structures 111 a,121 a, 121 b, and 111 b may be partially buried in the first and secondmain surfaces 130 a and 130 b of the separator 130 as shown in FIG. 3.To this end, trenches T (see FIG. 5) for receiving the first throughfourth structures 111 a, 121 a, 121 b, and 111 b may be formed in thefirst and second main surfaces 130 a and 130 b of the separator 130, orthe first through fourth structures 111 a, 121 a, 121 b, and 111 b maybe buried in the first and second main surfaces 130 a and 130 b of theseparator 130 by pressing the first through fourth structures 111 a, 121a, 121 b, and 111 b after the first through fourth structures 111 a, 121a, 121 b, and 111 b are disposed.

As described with reference to FIG. 2, a solid electrolyte layer may befurther formed only on an active material layer of structures having onetype of polarity. In this case, adjacent structures having oppositepolarities may extend on the same surface of the separator 130 whilecontacting each other without being spaced apart from each other. Forexample, in FIG. 3, a solid electrolyte layer may be selectively formedonly on one of the second structures 111 a and the third structures 121b, and the second structures 111 a and the third structures 121 b may bearranged in parallel on the first main surface 130 a of the separator130 without being spaced apart from each other. Likewise, a solidelectrolyte layer may be selectively formed only on one of the secondstructures 121 a and the fourth structures 111 b, and in this case, thesecond structures 121 a and the fourth structures 111 b may be arrangedin parallel on the second main surface 130 b of the separator 130without being spaced apart from each other.

In FIG. 3, since the first through fourth structures 111 a, 121 a, 121b, and 111 b having 3D curved surfaces are disposed such that structureshaving opposite polarities face each other by crossing each other withthe separator 130 therebetween and also face each other on the same mainsurface of the separator 130, an interfacial surface area betweenelectrodes may be increased as compared to that of a simple conventionalplaner electrode assembly. Accordingly, energy density in the samevolume may be improved, and charge/discharge speed, charge/dischargeefficiency, and battery cycle characteristics may also be improved.

FIG. 4 is an exploded perspective view illustrating an electrodeassembly 300 of a battery, according to another embodiment of thepresent invention.

Referring to FIG. 4, the electrode assembly 300 includes first andsecond separators 130 a and 130 b which are stacked. Although the firstseparator 130 a and the second separator 130 b are illustrated in FIG.4, the present embodiment is not limited thereto and three or moreseparators may be stacked.

In the electrode assembly 300, the first structures 111 a constituting afirst electrode 310 a, the second structures 121 a constituting a secondelectrode 320 a, and the first separator 331 are the same as thosedescribed with reference to FIG. 1. Third structures 121 c on a mainsurface of the second separator 332 which is opposite to an interfacebetween the first separator 331 and the second separator 332, extend ina direction, for example, a y direction, to cross the first structures111 a extending in, for example, an x direction.

Also, the third structures 121 c may have polarity opposite to that ofthe first structures 111 a. For example, when the first electrode 310 ais a cathode, the third structures 121 c may be coupled to one anotherto constitute a second anode 320 c. The second electrode 320 a (referredto as a first anode) and the second anode 320 c may be coupled to eachother to constitute one common anode. Although not shown in FIG. 4,another separator may be stacked over the second separator 332, and thefirst electrode 310 a (referred to as a first cathode) may be coupled tostructures of a cathode on the another isolation form stacked on thesecond separator 332 to constitute one common cathode. The structure isexemplary, and a bipolar battery may be provided by appropriatelydetermining the number and arrangement of structures having oppositepolarities and coupling the structures.

FIG. 5 is an exploded perspective view illustrating an electrodeassembly 400 of a battery, according to another embodiment of thepresent invention.

Referring to FIG. 5, the electrode assembly 400 includes a plurality ofseparators, that is, first and second separators 431 and 432 which arestacked. Although the first separator 431 and the second separator 432are illustrated in FIG. 5, three or more separators may be stacked.

In the electrode assembly 400, for the first through fourth structures111 a, 121 a, 121 b, and 111 b respectively constituting electrodes 410a, 420 a, 420 b, and 410 b, the disclosure with reference to FIG. 3 maybe referred to. Additional Fifth and sixth structures 111 c and 121 c,which extend on a main surface of the second separator 432 which isopposite to interface between the first separator 431 and the secondseparator 432, extend in a direction, for example, a y direction, tocross the first structures 111 a and the third structures 121 b disposedunder the fifth and sixth structures 111 c and 121 c. The fifth andsixth structures 111 c and 121 c have opposite polarities, and may bedisposed on the main surface of the second separator 432 to alternatewith each other.

As described above with reference to FIG. 3, a solid electrolyte layermay be further formed only on an active material layer of each ofstructures having one polarity. In this case, adjacent structures havingopposite polarity may extend on the same main surface of the first andsecond separators 431 and 432 by contacting each other without beingspaced apart from each other.

Also, a cathode 410 c and an anode 420 c may be provided byappropriately combining groups of structures having different stackorders and extension directions, or a bipolar battery may be provided byselecting some of structures and electrically coupling the structures asdescribed above. As in FIGS. 4 and 5, since two or more separators arestacked and fibrous structures are arranged on interface and a mainsurface of the separators opposite to the interface, an interfacialelectrode area between adjacent structures having opposite polarities isincreased, thereby improving energy density, charge/discharge speed,charge/discharge efficiency, and battery cycle characteristics.

FIGS. 6A through 6C are perspective views illustrating an electrodeassembly 500 according to another embodiment of the present invention.

Referring to FIGS. 6A and 6B, each of a cathode 510M and an anode 520Mof the electrode assembly 500 includes a plurality of fibrous structureswhich have the same polarity and cross each other. The plurality offibrous structures 511 x and 511 y and 521 w and 521 z having the samepolarity may contact each other and may form grid structures,respectively. For example, the cathode 510M includes the plurality offibrous structures 511 x that extend in an x direction, and theplurality of fibrous structures 511 y that extend in another direction,that is, a y direction, to cross the structures 511 x. The anode 520Mincludes the plurality of fibrous structures 521 w and 521 z whichextend in different directions, that is, a w direction and a zdirection, and cross each other.

In the electrode assembly 500 of FIG. 6C, a first separator 531 isdisposed between the cathode 510M and the anode 520M, to electricallyisolate the cathode 110M and the anode 120M. The cathode 510M and theanode 520M may be aligned to be symmetrical with each other about thefirst separator 531. Alternatively, as shown in FIG. 6C, the gridstructures of the electrode 510M and 520M may be rotated such that thecathode 510M and the anode 520M cross each other without beingsymmetrical with each other. That is, the cathode 510M may be disposedsuch that the structures 511 x and 511 y are aligned in the w and zdirections, and the anode 520M may be disposed such that the structures521 w and 521 z are aligned in the x and y directions. In this case, aninterfacial area between structures may be increased when compared to acase where the cathode 510M and the anode 520M are accurately alignedwith each other.

In other example, the cathode 510M and the anode 520M may be aligned inthe same direction and their grid structures may be misaligned. Forexample, although not shown in FIGS. 6A through 6C, the cathode 510M andthe anode 520M may be offset such that both the structures 511 x and 511y of the cathode 510M and the structures 521 w and 521 z of the anode520M may be arranged in the x and y directions, and any one of thecathode 510M and the anode 520M may be moved in the x direction or the ydirection to misalign the grid structures. Also, an interfacial area maybe increased by combining the aforesaid rotation method and the movementmethod to misalign the grid structures of the cathode 510M and the anode120M.

In another example, as shown in FIG. 6C, a second separator 532 may bestacked over the first separator 531, and an electrode 530M havinganother grid structure may be disposed on a main surface of the secondseparator 532 which is opposite to interface between the first separator531 and the second separator 532. Accordingly, energy density may befurther improved. The additional electrode 530M may be an anode, and theelectrode 530M and the cathode 510M disposed under the electrode 530Mmay be aligned in such a manner as that described for the alignment ofthe cathode 510M and the anode 520M.

FIG. 7 is a perspective view illustrating an electrode assembly 600 of abattery, according to another embodiment of the present invention.

Referring to FIG. 7, in the electrode assembly 600, the first structures111 constituting a first electrode 610 and the second structures 121constituting a second electrode 620 cross each other as weft threads andwarp threads reciprocating through a separator 630. The right imageillustrates the electrode assembly 600 from which the separator 630 isnot shown in order to clearly show the first structures 111 and thesecond structures 121.

Since different structures are insulated by the separator 630, even whenthe electrode assembly 600 is deformed, the first and second structures111 and 121 may be prevented from being short-circuited. Energy densitymay be improved and insulation between the first and second structures111 and 121 may be improved by forming a solid electrolyte layer only onstructures having one polarity as described with reference to FIG. 2.Although not shown in FIG. 7, one or more separators may be furtherstacked over the separator 630 without departing from the scope of thepresent invention.

Also, as described above, when the first and second structures 111 and121 having fibrous structures cross each other in different directions,the first and second structures 111 and 121 may cross each other at apredetermined frequency, or at least some of the first and secondstructures 111 and 121 may cross each other at random. Since structureshaving one polarity are at least partially buried in structures havingopposite polarity, an interfacial area between the first electrode 610and the second electrode 620 may be increased, energy density may beimproved, and charge/discharge speed, charge/discharge efficiency, andlifetime may also be improved.

FIG. 8 is a perspective view illustrating an electrode assembly 700according to another embodiment of the present invention.

Referring to FIG. 8, the electrode assembly 700 includes, instead of aseparator, an isolation matrix 730 that has a thickness great enough forat least two electrodes 710 and 720 respectively including first andsecond structures 711 and 712 having opposite polarities to be embeddedin the isolation matrix 730. The isolation matrix 730 may be formed ofthe same material as those of the separators in the previousembodiments. In order to align the first and second structures 711 and712 in the isolation matrix 730, the isolation matrix 730 may beprovided by aligning the first and second structures 711 and 722 in asolution that is to be an isolation matrix and then coagulating thesolution. The isolation matrix 730 may be formed of an intrinsic solidpolymer electrolyte or a gel polymer electrolyte.

The first structures 711 passing through the isolation matrix 730 andextending in an x direction may be disposed on the same plane. Likewise,the second structures 721 passing through the isolation matrix 730 andextending in a y direction may be disposed on the same plane. The planeson which the first and second structures 711 and 712 having oppositepolarities are disposed are spaced apart from each other, and the firstand second structures 711 and 721 are separated from each other in theisolation matrix 730.

It would be understood by one of ordinary skill in the art that thefirst and second structures 711 and 721 passing through the isolationmatrix 730 may be stacked as two or more layers in the isolation matrix730, and two or more isolation matrixes 730 may be stacked. Since aninterfacial area between the first and second structures 711 and 722which are adjacent to each other is increased in a 3D manner, energydensity may be improved, and charge/discharge efficiency and batterycycle characteristics may also be improved.

Although structures having opposite polarities are spaced apart in FIG.8, a solid electrolyte layer such as an intrinsic solid polymerelectrolyte layer may be further formed only on the structures having aspecific one of two polarities, for example, the structures of an anode.In this case, structures having opposite polarities may extend to crossin the same direction or different directions without being spaced apartfrom each other. Alternatively, structures having the same polaritiesmay extend to cross in the same direction or different directions bycontacting each other without being spaced apart from each other.

FIG. 9 is a perspective view illustrating an electrode assembly 800according to another embodiment of the present invention.

Referring to FIG. 9, the electrode assembly 800 includes an isolationmatrix 830 that has a thickness great enough for first through fourthstructures 711 a, 721 a, 721 b, and 711 b having different polarities tobe stacked to cross each other in the isolation matrix 830. In order toalign the first through fourth structures 811 a, 821 a, 821 b, and 811 bin the isolation matrix 830, the isolation matrix 830 may be provided byaligning the first through fourth structures 811 a, 821 a, 821 b, and811 b in a solution that is to be an isolation matrix and thencoagulating the solution. The isolation matrix 830 may be formed of asolid polymer electrolyte or a gel polymer electrolyte.

The first through fourth structures 811 a, 821 a, 821 b, and 811 b passthrough the isolation matrix 830. The electrode assembly 800 isdifferent from the electrode assembly 700 in that the electrode assembly800 further includes the third structures 821 b that extend in an xdirection on the same plane as the first structures 811 a extending inthe x direction to alternate with the first structures 811 a and havepolarity opposite to polarity of the first structures 811 a. Likewise,the electrode assembly 800 further includes the fourth structures 811 bthat extend in a y direction on the same plane as the second structures821 a passing through the isolation matrix 830 and extending in the ydirection to alternate with the second structures 821 a and havepolarity opposite to polarity of the second structures 821 a. Onecathode and an anode may be provided outside a battery by combiningstructures having the same polarity, or a bipolar battery may beprovided by coupling structures having opposite polarities in thebattery.

The embodiments may be combined unless being contradictory withoutdeparting from the scope of the invention. For example, in the electrodeassembly 600 of FIG. 7, the isolation matrix 730 (see FIG. 8) may beused instead of the separator 630, and the first and second structures111 and 121 which are weft threads and warp threads illustrated in theright image of FIG. 7 may be buried as at least one layer in theisolation matrix 730. Also, in the electrode assembly 500 of FIG. 6C,the first and second structures 511 x and 511 y may cross each other asweft threads and warp threads, and the third and fourth structures 521 wand 521 z may cross each other as weft threads and warp threads. In thiscase, a solid electrolyte layer may be selectively further formed onlyon any one electrode, preferably, an electrode whose volume changeduring charging/discharging is the smaller electrode among the cathode510M including the structures 511 x and 511 y and the anode 520Mincluding the structures 521 w and 521 z. Also, it would be understoodthat two or more structures having different arrangements may becombined.

FIG. 10 is a perspective view illustrating an electrode assembly 900according to another embodiment of the present invention.

Referring to FIG. 10, the electrode assembly 900 constituting a batteryincludes a first electrode 920 including a plurality of first structures121 having fibrous shapes, and a second electrode 910 having a plannershape and a polarity opposite to polarity of the first structures 121.The second electrode 910 facing the first electrode 920 including thefirst structures 121 is different from other fibrous structures in thatthe second electrode 910 has a planner shape.

A thickness w of each of the first structures 121 may range from 400 μmto 2,000 μm, and may be appropriately determined according to a field towhich the battery is applied. A distance d between the first structures121 may be greater than 0 μm and less than 1,000 μm, and preferably from2 μm to 400 μm. In order to increase an interfacial surface area betweenthe first and second electrodes 920 and 910, the distance d may begreater than 0 μm and less than the thickness w of each of the firststructures 121.

A separator 930 is provided between the first electrode 910 and thesecond electrodes 920. The separator 930 may be a micro-porous film, awoven fabric, a nonwoven fabric, an intrinsic solid polymer electrolytefilm, or a gel solid polymer electrolyte film as described above. Theintrinsic solid polymer electrolyte film may include a straight chainpolymer material or a cross-linked polymer material. The gel polymerelectrolyte film may be any one of a plasticizer-containing polymerincluding salt, a filler-container polymer, and a pure polymer, or acombination thereof.

The first structures 121 extending in parallel in one direction may beelectrically connected to one another to constitute one electrode, forexample, a cathode. In this case, the second electrode 910 having theplanner shape may be an anode.

FIG. 11 is a perspective view illustrating an electrode assembly 1000according to another embodiment of the present invention.

Referring to FIG. 11, the electrode assembly 1000 is different from theelectrode assembly 1000 of FIG. 10 in that the first structures 121further extend to surround a second electrode 1010 and thus to face bothmain surfaces of the second electrode 1010 having a planner shape. Inorder to separate a first electrode 1020 including the first structures121 from the second electrode 1010 having the planner shape, separators1030 a and 1030 b may be disposed between the first structures 121 andthe both main surfaces of the second electrode 1010. A plurality ofseparators may be provided as shown in FIG. 11, and one plannerseparator may be folded to contact the both main surfaces of the secondelectrode 1010. Alternatively, a separator may be provided by providingan intrinsic solid polymer electrolyte or a gel solid polymerelectrolyte to surround the second electrode 1010.

Since the first structures 121 are wound around the both main surfacesof the second electrode 1010, an interfacial surface area between thefirst and second electrodes 10120 and 1010 may be increased.Accordingly, energy density in the same volume may be improved, andcharge/discharge efficiency and battery cycle characteristics may alsobe improved. Although the first structures 121 surround the secondelectrode 1010 by being wound one time in FIG. 11, the first structures121 may be wound two or more times without departing from the scope ofthe present invention. In this case, only one first structure, insteadof a plurality of first structures, may be provided by being spirallywound.

FIG. 12 is a perspective view illustrating an electrode assembly 1100according to another embodiment of the present invention.

Referring to FIG. 12, an electrode 1121M of the electrode assembly 1100includes a plurality of fibrous structures 1121 x and 1121 y having thesame polarity and crossing each other. The plurality of fibrousstructures 1121 x and 1121 y having the same polarity may contact eachother to form a grid structure. Another electrode 1110 of the electrodeassembly 1000 has a planner shape like the second electrode 910 of FIG.10. The electrode 1121M may be an anode and the electrode 1110 may be acathode. A separator 1130 is provided between the electrode 1121Mincluding the structures 1121 x and 1121 y and the electrode 1110 havingthe planner shape.

FIG. 13 is a perspective view illustrating an electrode assembly 1200according to another embodiment of the present invention.

Referring to FIG. 13, the electrode assembly 1200 includes firststructures 121 a and further includes second structures 121 b thatextend in a direction different from a direction in which the firststructures 121 a extend to cross the first structures 121 a and have thesame polarity as that of the first structures 121 a, when compared tothe electrode assembly 1100 of FIG. 12. However, in FIG. 13, the firststructures 121 a and the second structures 121 b cross each other asweft threads and warp threads.

Another electrode 1210 of the electrode assembly 1200 has a plannershape. The electrode 1210 is a cathode, and the electrode 1220 includingthe first and second structures 121 a and 121 b is an anode. A separator1230 is provided between the electrode 1210 having the planner shape andthe electrode 1220 including the structures 121 a and 121 b.

After electrode assemblies are formed, a separator or an isolationmatrix may be impregnated in an appropriate electrolyte to be activated.Alternatively, when the separator or the isolation matrix is formed of agel or intrinsic solid polymer electrolyte, the separator or theisolation matrix may be activated without being impregnated.

As described above, since at least one of a cathode and an anodeincludes a plurality of fibrous structures, an interfacial surface areabetween electrodes may be increased and an electrode assembly which isthin and whose shape is easily changed may be easily made. It would beunderstood by one of ordinary skill in the art that the embodiments maybe combined unless being contradictory without departing from the scopeof the present invention. For example, in FIG. 13, first and secondstructures crossing each other as weft threads and warp threads mayextend to reciprocate through a separator.

A battery whose shape is easily changed may be provided by changingshapes of fibrous structures whose shapes may be easily changed,adjusting areas of the structures to adjust capacity, and folding,bending, or stacking the structures. For example, the battery may beused as a small battery by being attached to clothes, bags, etc., or maybe used as a large or medium battery of vehicles by having highcapacity.

Also, according to the embodiments, since a interfacial area isincreased in a 3D manner and charge/discharge efficiency is improved, abattery may be manufactured by using a small amount of cathode material.In the case of a lithium ion battery, considering its limited reserves,according to the embodiments, a battery that may obtain the same energywith less lithium may be provided.

While the present invention has been particularly shown and describedwith reference to exemplary embodiments thereof, it will be understoodby those of ordinary skill in the art that various changes in form anddetails may be made therein without departing from the spirit and scopeof the present invention as defined by the following claims.

1. An electrode assembly comprising: a first electrode comprising aplurality of first structures that have fibrous shape and extend in afirst direction; a second electrode comprising a plurality of secondstructures that have fibrous shape and polarity opposite to polarity ofthe first structures, and extend in a second direction different fromthe first direction; and a first separator that is disposed between thefirst structures and the second structures which cross each other, andseparates the first structures from the second structures.
 2. Theelectrode assembly of claim 1, wherein the first structures extend on afirst main surface of the first separator to be spaced apart from oneanother, and the second structures extend on a second main surface ofthe first separator which is opposite to the first main surface to bespaced apart from one another.
 3. The electrode assembly of claim 2,further comprising: a third electrode comprising a plurality of thirdstructures that have fibrous shape and polarity opposite to the polarityof the first structures, and extend on the first main surface of thefirst separator in the first direction to alternate with the firststructures; and a fourth electrode comprising a plurality of fourthstructures that have fibrous shape and polarity opposite to the polarityof the second structures, and extend on the second main surface of thefirst separator in the second direction to alternate with the secondstructures, wherein the third structures and the fourth structures whichcross each other are separated from each other by the first separator.4. The electrode assembly of claim 3, wherein at least some of the firstthrough fourth structures are partially or totally buried in the firstor second main surface of the first separator.
 5. The electrode assemblyof claim 1, further comprising: at least one second separator that isstacked on the first separator to form a multi-layered structure; and athird electrode comprising a plurality of third structures that extendon a main surface of the second separator which is opposite to aninterface between the first separator and the second isolation, and havefibrous shape and polarity opposite to polarity of structures of theinterface, wherein the third structures and the structures on theinterface cross each other.
 6. The electrode assembly of claim 3,further comprising: at least one second separator that is stacked on thefirst separator to form a multi-layered structure; a fifth electrodecomprising a plurality of fifth structures that extend on a main surfaceof the second separator which is opposite to an interface between thefirst separator and the second separator, and have fibrous shape andpolarity opposite to polarity of structures on the interface, whereinthe fifth structures and the structures on the interface cross eachother; and a sixth electrode comprising a plurality of sixth structuresthat have fibrous shape and polarity opposite to the polarity of thefifth structures, extend on the other main surface of the secondseparator to alternate with the fifth structures, wherein the sixthstructures and the structures on the interface cross each other.
 7. Theelectrode assembly of claim 6, wherein at least some of the firstthrough sixth structures are partially or totally buried in the first orsecond separator.
 8. The electrode assembly of claim 1, wherein thefirst structures and the second structures cross each other as weftthreads and warp threads reciprocating through the first separator. 9.The electrode assembly of claim 1, wherein each of the first structuresand the second structures comprises a current collector core and anactive material layer that surrounds the current collector core.
 10. Theelectrode assembly of claim 9, wherein only ones of the first structuresand the second structures selectively further comprise a solidelectrolyte layer that surrounds the active material layer.
 11. Theelectrode assembly of claim 1, wherein a thickness of each of the firstand second structures ranges from 400 μm to 2,000 μm, and a distancebetween the first and second structures ranges from 2 μm to 400 μm. 12.The electrode assembly of claim 1, wherein a distance between the firstand second structures is less than a thickness of each of the first andsecond structures.
 13. The electrode assembly of claim 1, wherein thefirst separator comprises any one of a micro-porous film, a wovenfabric, a nonwoven fabric, an intrinsic solid polymer electrolyte film,a gel solid polymer electrolyte film, and a combination thereof. 14-19.(canceled)
 20. An electrode assembly comprising: an isolation matrix; afirst electrode comprising a plurality of first structures that havefibrous shape, and pass through the isolation matrix and extend on afirst plane in the isolation matrix in a first direction to be spacedapart from one another; and a second electrode comprising a plurality ofsecond structures that have fibrous shape, and pass through theisolation matrix and extend on a second plane, which is spaced apartfrom the first plane to be parallel to the first plane, in the isolationmatrix in a second direction different from the first direction to crossthe first structures.
 21. The electrode assembly of claim 20, furthercomprising: a third electrode comprising a plurality of third structuresthat have fibrous shape and polarity opposite to polarity of the firststructures, and extend on the first plane in the first direction toalternate with the first structures; and a fourth electrode comprising aplurality of fourth structures that have fibrous shape and polarityopposite to polarity of the second structures, and extend on the secondplane in the second direction to alternate with the second structures.22. The electrode assembly of claim 20, wherein a plurality of the firstplanes and a plurality of the second planes are provided to form amulti-layered structure.
 23. The electrode assembly of claim 20, whereineach of the first structures and the second structures comprises acurrent collector core and an active material layer that surrounds thecurrent collector core.
 24. The electrode assembly of claim 20, whereinonly ones of the first structures and the second structures selectivelyfurther comprise a solid electrolyte layer that surrounds the activematerial layer.
 25. The electrode assembly of claim 20, wherein theisolation matrix is any one of a micro-porous film, a woven fabric, anonwoven fabric, an intrinsic solid polymer electrolyte film, a gelsolid polymer electrolyte film, and a combination thereof.
 26. Theelectrode assembly of claim 20, wherein a thickness of each of the firstand second structures ranges from 400 μm to 2,000 μm, and a distancebetween the first and second structures ranges from 2 μm to 400 μm. 27.The electrode assembly of claim 20, wherein a distance between the firstand second structures is less than a thickness of each of the first andsecond structures.
 28. An electrode assembly comprising: an isolationmatrix; a first electrode comprising a plurality of first structuresthat have fibrous shape, and pass through the isolation matrix andextend on a first plane in the isolation matrix in a first direction tobe spaced apart from one another; and a second electrode comprising aplurality of second structures that have fibrous shape, and pass throughthe isolation matrix and extend on the first plane in a second directiondifferent from the first direction such that the second structures andthe first structures cross each other as weft threads and warp threads.29. The electrode assembly of claim 28, further comprising a secondcathode and a second anode respectively comprising a plurality of thirdstructures and a plurality of fourth structures which have fibrousshapes and extend on a second plane, which is spaced apart from thefirst plane to be parallel to the first plane, in the isolation matrixsuch that the third and fourth structures and the first and secondstructures cross each other as weft threads and warp threads.
 30. Theelectrode assembly of claim 28, wherein each of the first structures andthe second structures comprises a current collector core and an activematerial that surrounds the current collector core.
 31. The electrodeassembly of claim 28, wherein only ones of the first structures and thesecond structures selectively further comprise a solid electrolyte layerthat surrounds the active material layer.
 32. The electrode assembly ofclaim 28, wherein the isolation matrix comprises an intrinsic solidpolymer electrolyte film or a gel solid polymer electrolyte film. 33.The electrode assembly of claim 28, wherein a thickness of each of thefirst and second structures ranges from 400 μm to 2,000 μm, and adistance between the first and second structures ranges from 2 μm to 400μm.
 34. The electrode assembly of claim 28, wherein a distance betweenthe first and second structures is less than a thickness of the firstand second structures.
 35. An electrode assembly comprising: a firstelectrode comprising a plurality of first structures that have fibrousshapes and extend in a first direction; a second electrode that has aplanar shape and a polarity opposite to polarities of the firststructures; and a separator that is disposed between the first electrodeand the second electrode.
 36. The electrode assembly of claim 35,further comprising a third electrode comprising a plurality of secondstructures that have fibrous shape and the same polarity as the polarityof the first structures, and extend in a second direction different fromthe first direction to cross the first structures.
 37. The electrodeassembly of claim 36, wherein the first structures and the secondstructures cross each other as weft threads and warp threads.
 38. Theelectrode assembly of claim 37, wherein the first and second structuresreciprocate through the separator.
 39. The electrode assembly of claim35, wherein the first structures further extend to surround both mainsurfaces of the second electrode.
 40. The electrode assembly of claim35, wherein a thickness of each of the first structures ranges from 400μm to 2,000 μm, and a distance between the first structures ranges from2 μm to 400 μm.
 41. The electrode assembly of claim 35, wherein adistance between the first structures is less than a thickness of eachof the first structures.
 42. The electrode assembly of claim 1, whereinthe first electrode further comprises a plurality of third structuresthat have fibrous shape and the same polarity as polarity of the firststructures and extend in a third direction different from the firstdirection to cross the first structures, and the second electrodefurther comprises a plurality of fourth structures that have fibrousshape and the same polarity as polarity of the second structures andextend in a fourth direction different from the second direction tocross the third structures.
 43. The electrode assembly of claim 42,wherein the first electrode and the second electrode are rotated oroffset such that the first electrode and the second electrode are notsymmetrical with each other.
 44. The electrode assembly of claim 42,wherein the first and third structures cross each other as weft threadsand warp threads, and the second and fourth structures cross each otheras weft threads and warp threads.
 45. The electrode assembly of claim42, wherein each of the first through fourth structures comprises acurrent collector core and an active material layer that surrounds thecurrent collector core.